{"id":5516,"date":"2015-08-02T16:01:31","date_gmt":"2015-08-02T07:01:31","guid":{"rendered":"http:\/\/bamlab.ok-japan.com\/?p=5516"},"modified":"2019-11-01T16:01:51","modified_gmt":"2019-11-01T07:01:51","slug":"%e3%81%82%e3%81%82%e3%80%81%e5%b8%9d%e5%9b%bd%e3%83%9b%e3%83%86%e3%83%ab%e3%83%9e%e3%83%bc%e3%82%ac%e3%83%aa%e3%83%b3","status":"publish","type":"post","link":"https:\/\/bamboolab.yamasatoagr.com\/?p=5516","title":{"rendered":"\u3042\u3042\u3001\u5e1d\u56fd\u30db\u30c6\u30eb\u30de\u30fc\u30ac\u30ea\u30f3"},"content":{"rendered":"\n<p>\u3000\u6709\u6a5f\u5316\u5408\u7269\u306e\u4e2d\u306b\u306f\u3001\u5206\u5b50\u5f0f\u304c\u540c\u3058\u3067\u3042\u3063\u3066\u3082\u69cb\u9020\u304c\u7570\u306a\u308b\u5316\u5408\u7269\u7fa4\u306f\u3044\u304f\u3089\u3067\u3082\u5b58\u5728\u3059\u308b\u3002\u305d\u3046\u3057\u305f\u95a2\u4fc2\u306b\u3042\u308b\u5316\u5408\u7269\u7fa4\u3092\u7570\u6027\u4f53\u3068\u3044\u3046\u696d\u754c\u7528\u8a9e\u3067\u8868\u3059\u306e\u3060\u304c\u3001\u3053\u306e\u7570\u6027\u4f53\u306b\u3082\u3044\u308d\u3044\u308d\u306a\u7a2e\u985e\u304c\u5b58\u5728\u3059\u308b\u3002\u9ad8\u6821\u306e\u5316\u5b66\u306b\u65bc\u3044\u3066\u4e00\u5fdc\u6559\u3048\u3089\u308c\u3066\u306f\u3044\u308b\u306e\u3060\u304c\u3001\u5e7e\u4f55\u7570\u6027\u4f53\u3001\u5149\u5b66\u7570\u6027\u4f53\u3068\u3044\u308f\u308c\u3066\u3001\u3059\u3050\u306b\u8aac\u660e\u3067\u304d\u308b\u4eba\u306f\u3042\u307e\u308a\u591a\u304f\u306f\u306a\u3044\u3002<\/p>\n\n\n\n<p>\u3000\u69cb\u9020\u7570\u6027\u4f53\u3092\u542b\u3081\u3066\u3001\u305d\u308c\u305e\u308c\u306e\u8aac\u660e\u306f\u4ed6\u306b\u8b72\u308b\u3068\u3057\u3066\u3001\u3053\u3053\u3067\u306f\u70ad\u7d20-\u70ad\u7d20\u9593\u306e\u4e8c\u91cd\u7d50\u5408\u306b\u7531\u6765\u3059\u308b\u5e7e\u4f55\u7570\u6027\u4f53\u3001\u6b63\u5f0f\u306b\u306f<em>cis-trans<\/em>\u7570\u6027\u4f53\u306b\u3064\u3044\u3066\u5c11\u3057\u8ff0\u3079\u3066\u307f\u305f\u3044\u3002\u7e70\u308a\u8fd4\u3057\u306e\u3088\u3046\u3060\u304c\u3001\u3053\u306e\u7570\u6027\u306f\u70ad\u7d20\u70ad\u7d20\u9593\u306e\u4e8c\u91cd\u7d50\u5408\u306e\u6027\u8cea\u306b\u7531\u6765\u3059\u308b\u3002\u4f59\u308a\u306b\u521d\u6b69\u7684\u306a\u8a71\u3092\u3059\u308b\u306e\u306f\u3053\u306e\u30d6\u30ed\u30b0\u306e\u8aad\u8005\u306b\u5bfe\u3057\u3066\u5931\u793c\u306b\u5f53\u305f\u308b\u3060\u308d\u3046\u3002\u305d\u3053\u3067\u3001\u4e8c\u3064\u306e\u70ad\u7d20\u4e0a\u306b\u3042\u308b\u6df7\u6210\u306b\u53c2\u52a0\u3057\u3066\u3044\u306a\u3044\uff50\u8ecc\u9053\u306e\u9593\u3067\u6210\u7acb\u3057\u3066\u3044\u308b\u03c0\u7d50\u5408\u306e\u6027\u8cea\u6545\u306b\u3001\u70ad\u7d20-\u70ad\u7d20\u3092\u8ef8\u3068\u3059\u308b\u56de\u8ee2\u304c\u3067\u304d\u306a\u3044\u3053\u3068\u3092\u65e2\u77e5\u306e\u77e5\u8b58\u3068\u3057\u3066\u6271\u3046\u3053\u3068\u306b\u3059\u308b\u3002\u9ad8\u6821\u306b\u65bc\u3044\u3066\u306f\u3001\u3053\u306e\u5e7e\u4f55\u7570\u6027\u306e\u4f8b\u3068\u3057\u3066\u30de\u30ec\u30a4\u30f3\u9178\u3068\u30d5\u30de\u30eb\u9178\u3092\u63a1\u7528\u3059\u308b\u5834\u5408\u304c\u591a\u304b\u3063\u305f\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter\"><a href=\"http:\/\/bamboolab.ok-japan.com\/?attachment_id=2814\" rel=\"attachment wp-att-2814\"><img decoding=\"async\" src=\"http:\/\/bamboolab.ok-japan.com\/wp-content\/uploads\/2015\/08\/\u30b9\u30af\u30ea\u30fc\u30f3\u30b7\u30e7\u30c3\u30c8\uff082015-08-02-15.16.04\uff09.png\" alt=\"\u30b9\u30af\u30ea\u30fc\u30f3\u30b7\u30e7\u30c3\u30c8\uff082015-08-02 15.16.04\uff09\" class=\"wp-image-2814\"\/><\/a><figcaption>\u30b7\u30b9-\u30c8\u30e9\u30f3\u30b9\u7570\u6027\u4f53\u306e\u4f8b<\/figcaption><\/figure><\/div>\n\n\n\n<p>\u3000\u8a18\u61b6\u304c\u5b9a\u304b\u3067\u306f\u306a\u3044\u304c\u30012-\u30d6\u30c6\u30f3\u3092\u4f8b\u3068\u3057\u3066\u63a1\u7528\u3057\u305f\u6559\u79d1\u66f8\u304c\u3042\u3063\u305f\u3088\u3046\u306a\u6c17\u3082\u3059\u308b\u3002<em>cis-trans<\/em>\u7570\u6027\u4f53\u306f\u3001\u4e8c\u91cd\u7d50\u5408\u306b\u5bfe\u3057\u3066\u4e3b\u9396\u3068\u306a\u308b\u70ad\u7d20\u9aa8\u683c\u304c\u540c\u3058\u5074\u306b\u3042\u308b\u5834\u5408\u3092<em>cis<\/em>\u4f53\u3001\u53cd\u5bfe\u5074\u306b\u3042\u308b\u5834\u5408\u3092 <em>trans<\/em>\u4f53\u3068\u3057\u3066\u3044\u308b\u3002IUPAC\u3067\u5b9a\u3081\u3089\u308c\u3066\u3044\u308b\u7f6e\u63db\u57fa\u306e\u9806\u4f4d\u5247\u3092\u7528\u3044\u3066\u3001\u3053\u306e\u5b9a\u7fa9\u3092\u3082\u3046\u5c11\u3057\u62e1\u5927\u3057\u305f<em>EZ<\/em>\u8868\u793a\u6cd5\u304c\u4e0a\u4f4d\u898f\u5247\u3068\u3057\u3066\u5b58\u5728\u3059\u308b\u306e\u3067\u3069\u3053\u304b\u3067\u76ee\u3092\u901a\u3057\u3066\u304a\u3044\u3066\u4e0b\u3055\u3044\u3002<\/p>\n\n\n\n<p>\u3000\u305d\u3053\u3067<em>cis-trans<\/em>\u7570\u6027\u4f53\u306e\u8a71\u3060\u304c\u3001\u69cb\u9020\u304c\u9055\u3046\u306e\u3060\u304b\u3089\u5f53\u7136\u305d\u308c\u3089\u306e\u6027\u8cea\u3082\u7570\u306a\u308b\u3002\u30de\u30ec\u30a4\u30f3\u9178\u306epKa 1\u3001 pKa2\u306f\u3001\u305d\u308c\u305e\u308c1.84 \u30015.83 \u30d5\u30de\u30eb\u9178\u306e pKa1\u3001pKa2\u306f\u3001\u305d\u308c\u305e\u308c3.07\u30014.58 \u3067\u3042\u308b\u3057\u3001\u30de\u30ec\u30a4\u30f3\u9178\u306f\u52a0\u71b1\u3059\u308b\u3068\u5bb9\u6613\u306b\u7121\u6c34\u30de\u30ec\u30a4\u30f3\u9178\u3092\u5f62\u6210\u3059\u308b\u304c\u3001\u30d5\u30de\u30eb\u9178\u306f\u6607\u83ef\u3057\u3066\u3057\u307e\u3046\u3002\u6c34\u306b\u5bfe\u3059\u308b\u6eb6\u89e3\u5ea6\u3082\u9055\u3046\u3057\u3001\u878d\u70b9\u3082\u9055\u3046\u3002\u5f93\u3063\u3066\u3001\u751f\u7269\u306b\u5bfe\u3059\u308b\u4f5c\u7528\u3082\u7570\u306a\u308b\u308f\u3051\u3067\u3042\u308b\u3002\u30a2\u30d6\u30b7\u30b8\u30f3\u9178\u3067\u3042\u3063\u3066\u30822-<em> cis<\/em>\u4f53\u304c\u690d\u7269\u30db\u30eb\u30e2\u30f3\u3068\u3057\u3066\u50cd\u304f\u306e\u3067\u3042\u3063\u3066\u30012-<em> trans<\/em>\u4f53\u306f\u305d\u3046\u3067\u306f\u306a\u3044\u3002\u751f\u7269\u306b\u3068\u3063\u3066<em>cis-<\/em>\u4f53\u3068<em>trans<\/em>\u4f53\u306f\u5225\u306e\u30e2\u30ce\u3067\u3042\u308b\u3002<\/p>\n\n\n\n<p>\u3000\u9175\u7d20\u306e\u6d3b\u6027\u90e8\u4f4d\u3084\u60c5\u5831\u4f1d\u9054\u7cfb\u3067\u50cd\u304f\u53d7\u5bb9\u4f53\u306e\u591a\u304f\u304c\u3001<em>cis-trans<\/em>\u7570\u6027\u4f53\u3060\u3051\u3067\u306a\u304f\u3001\u3082\u3063\u3068\u4f3c\u3066\u3044\u308b\u3088\u3046\u306b\u898b\u3048\u308b\u5149\u5b66\u7570\u6027\u4f53\u3092\u8b58\u5225\u3059\u308b\u306e\u3060\u304b\u3089\u3001<em>cis-trans<\/em>\u7570\u6027\u4f53\u9593\u3067\u751f\u7406\u6d3b\u6027\u306b\u5dee\u304c\u3042\u3063\u3066\u3082\u4f55\u3089\u4e0d\u601d\u8b70\u3067\u306f\u306a\u3044\u3002\u3068\u306f\u3044\u3048\u3001\u3044\u307e\u9a12\u304c\u308c\u3066\u3044\u308b\u30c8\u30e9\u30f3\u30b9\u8102\u80aa\u9178\u554f\u984c\u306f\u3001\u3069\u3053\u306b\u554f\u984c\u304c\u3042\u308b\u306e\u304b\u3044\u307e\u3072\u3068\u3064\u7406\u89e3\u3067\u304d\u306a\u3044\u3002\u3088\u3046\u3084\u304f\u6765\u305f\u304b\u3068\u30cb\u30f3\u30de\u30ea\u3057\u3066\u3044\u308b\u8aad\u8005\u3082\u3044\u308b\u3068\u63a8\u5bdf\u3059\u308b\u304c\u3001\u8ab0\u304c\u4f55\u306e\u76ee\u7684\u3067\u3053\u306e\u9a12\u304e\u3092\u717d\u3063\u3066\u3044\u308b\u306e\u304b\u7406\u89e3\u306b\u82e6\u3057\u3093\u3067\u3044\u308b\u3002<\/p>\n\n\n\n<p>\u3000\u539f\u56e0\u306e1\u3064\u306f<em>trans&nbsp;<\/em>\u8102\u80aa\u9178\u306b\u3042\u308b\u3002<em>trans&nbsp;<\/em>\u8102\u80aa\u9178\u3068\u306f\u4f55\u3067\u3042\u308b\u304b\u306b\u3064\u3044\u3066\u3001\u4f55\u3068\u306a\u304f\u5206\u304b\u308a\u96e3\u3044\u306e\u3067\u3042\u308b\u3002\u30d2\u30c8\u304c\u6442\u53d6\u3059\u308b\u4e0d\u98fd\u548c\u8102\u80aa\u9178\u306b\u306f\u3001\u591a\u304f\u306e\u7a2e\u985e\u304c\u3042\u308b\u3002\u4f8b\u3048\u3070\u3001\u30df\u30ea\u30b9\u30c8\u30ec\u30a4\u30f3\u9178\u300a(<em>Z<\/em>)-tetradec-9-enoic acid\u300b\u3001\u30d1\u30eb\u30df\u30c8\u30ec\u30a4\u30f3\u9178\u300a(<em>Z<\/em>)-hexadec-9-enoic acid\u300b\u3001\u30aa\u30ec\u30a4\u30f3\u9178\u300a&nbsp;(<em>Z<\/em>)-octadec-9-enoic acid\u300b\u3001\u30d0\u30af\u30bb\u30f3\u9178\u300a(<em>Z<\/em>)-octadec-11-enoic acid\u300b\u3001\u30ac\u30c9\u30ec\u30a4\u30f3\u9178\u300a(<em>Z<\/em>)-icos-9-enoic acid\u300b\u3001\u30a8\u30a4\u30b3\u30bb\u30f3\u9178\u300a(<em>Z<\/em>)-icos-11-enoic acid\u300b\u3001\u30a8\u30eb\u30ab\u9178\u300a&nbsp;(<em>Z<\/em>)-docos-13-enoic acid\u300b\u306a\u30691\u3064\u306e\u4e8c\u91cd\u7d50\u5408\u3092\u6301\u3064\u4e0d\u98fd\u548c\u8102\u80aa\u9178\u985e\u3001\u30ea\u30ce\u30fc\u30eb\u9178\u300a(9<em>Z<\/em>,12<em>Z<\/em>)-octadeca-9,12-dienoic acid\u300b\u3001\u30a8\u30a4\u30b3\u30b5\u30b8\u30a8\u30f3\u9178\u300a(11<em>Z<\/em>,14<em>Z<\/em>)-icosa-11,14-dienoic acid\u300b\u3001\u30c9\u30b3\u30b5\u30b8\u30a8\u30f3\u9178\u300a(13<em>Z<\/em>,16<em>Z<\/em>)-docosa-13,16-dienoic acid\u300b\u306a\u30692\u3064\u306e\u4e8c\u91cd\u7d50\u5408\u3092\u6301\u3064\u4e0d\u98fd\u548c\u8102\u80aa\u9178\u985e\u3001\u03b1-\u30ea\u30ce\u30ec\u30f3\u9178\u300a(9<em>Z<\/em>,12<em>Z<\/em>,15<em>Z<\/em>)-octadeca-9,12,15-trienoic acid\u300b\u3001\u03b3-\u30ea\u30ce\u30ec\u30f3\u9178\u300a(6<em>Z<\/em>,9<em>Z<\/em>,12<em>Z<\/em>)-octadeca-6,9,12-trienoic 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